A Textbook of Inorganic Chemistry – Volume 1

A Textbook of Inorganic Chemistry – Volume 1
Author :
Publisher : Dalal Institute
Total Pages : 482
Release :
ISBN-10 : 9788193872000
ISBN-13 : 8193872002
Rating : 4/5 (002 Downloads)

Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal

Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory; dπ -pπ bonds; Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions; Trends in stepwise constants; Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand; Chelate effect and its thermodynamic origin; Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes; Mechanisms for ligand replacement reactions; Formation of complexes from aquo ions; Ligand displacement reactions in octahedral complexes- acid hydrolysis, base hydrolysis; Racemization of tris chelate complexes; Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes; The trans effect; Theories of trans effect; Mechanism of electron transfer reactions – types; outer sphere electron transfer mechanism and inner sphere electron transfer mechanism; Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory; Molecular orbital theory: octahedral, tetrahedral or square planar complexes; π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals; Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states); Calculation of Dq, B and β parameters; Effect of distortion on the d-orbital energy levels; Structural evidence from electronic spectrum; John-Tellar effect; Spectrochemical and nephalauxetic series; Charge transfer spectra; Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry; Guoy’s method for determination of magnetic susceptibility; Calculation of magnetic moments; Magnetic properties of free ions; Orbital contribution, effect of ligand-field; Application of magneto-chemistry in structure determination; Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes; Wade’s rules; Carboranes; Metal carbonyl clusters - low nuclearity carbonyl clusters; Total electron count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls: structure and bonding; Vibrational spectra of metal carbonyls for bonding and structure elucidation; Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.


A Textbook of Inorganic Chemistry – Volume 1 Related Books

A Textbook of Inorganic Chemistry – Volume 1
Language: en
Pages: 482
Authors: Mandeep Dalal
Categories: Science
Type: BOOK - Published: 2017-01-01 - Publisher: Dalal Institute

DOWNLOAD EBOOK

An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a pa
Essentials of Inorganic Chemistry
Language: en
Pages: 290
Authors: Katja A. Strohfeldt
Categories: Science
Type: BOOK - Published: 2015-02-16 - Publisher: John Wiley & Sons

DOWNLOAD EBOOK

A comprehensive introduction to inorganic chemistry and, specifically, the science of metal-based drugs, Essentials of Inorganic Chemistry describes the basics
A Textbook of Inorganic Chemistry
Language: en
Pages: 984
Authors: Arihant Experts
Categories: Study Aids
Type: BOOK - Published: 2019-02-14 - Publisher:

DOWNLOAD EBOOK

Getting hold of the concepts of Inorganic Chemistry for an adequate study preparation of JEE Main and Advanced requires one to go beyond their traditional textb
Inorganic Chemistry
Language: en
Pages: 848
Authors: J. E. House
Categories: Science
Type: BOOK - Published: 2012-10-30 - Publisher: Academic Press

DOWNLOAD EBOOK

This textbook provides essential information for students of inorganic chemistry or for chemists pursuing self-study. The presentation of topics is made with an
Principles of Inorganic Chemistry
Language: en
Pages: 761
Authors: Brian W. Pfennig
Categories: Science
Type: BOOK - Published: 2015-03-30 - Publisher: John Wiley & Sons

DOWNLOAD EBOOK

Aimed at senior undergraduates and first-year graduate students, this book offers a principles-based approach to inorganic chemistry that, unlike other texts, u